There are 42 characters in the game. Each character has one Ultimate Attack (Sanji has two – an alternate one when fighting girls). To activate the Ultimate simply press the right stick twice. One time to awaken, a second time to trigger the Ultimate. You must have a full burst gauge for this.

You can buy all characters in the shop. You can also get some for free by beating all story missions. But this is not a strict requirement, you could buy all of them without doing the story. In this video I show them in the same order as character select.

There are also two trophies for this. “See You on the High Seas” for performing 30 Ultimates and “I’ve got allies!!!!” for unlocking all battle chars.

TIMELINE:

#1 – Monkey D. Luffy – 0:05
#2 – Whitebeard – 0:30
#3 – Phoenix Marco – 0:47
#4 – Portgas D Ace – 1:05
#5 – Diamond Joz – 1:21
#6 – Buggy – 1:37
#7 – Emporio Ivankov – 1:49
#8 – Jinbei – 2:03
#9 – Crocodile – 2:17
#10 – Boa Hancock – 2:30
#11 – Gekko Moriah – 2:48
#12 – Drakule Mihawk – 3:33
#13 – Bartholomew Kuma – 3:37
#14 – Sengoku – 3:49
#15 – Sakazuki Akainu – 4:20
#16 – Borsalino Kizaru – 4:41
#17 – Kuzan Aokiji – 4:57
#18 – Smoker (2 years ago) – 5:11
#19 – Blackbeard – 5:31
#20 – Shanks – 5:47
#21 – Luffy Gear 4 – 6:17
#22 – Roronoa Zoro – 6:53
#23 – Usopp – 7:14
#24 – Sanji – 7:25
#25 – Nami – 8:11
#26 – Tony Tony Chopper – 8:26
#27 – Nico Robin – 8:40
#28 – Cyborg Franky – 8:54
#29 – Brook – 9:08
#30 – Trafalgar Law – 9:27
#31 – Eustass Kid – 9:44
#32 – X Drake – 9:58
#33 – Bartolomeo – 10:16
#34 – DONQUIXOTE Doflamingo – 10:31
#35 – Issho Fujitora – 10:57
#36 – Jesus Burgees – 11:17
#37 – Smoker (new version) – 11:37
#38 – Bentham (Mr. 2 Bon Clay) – 11:57
#39 – Enel – 12:13
#40 – Perona (Ghost Princess) – 12:29
#41 – Sabo – 12:44
#42 – Koala – 13:03