There are 16 characters and 18 Critical Arts in Street Fighter 5. Each character has at least one of these moves (Ryu & Necalli have two). They are similar to Super Moves / Ultra Moves from Street Fighter IV. To activate them your CA bar must be full. You can find the button combination for each character in the “Command List” when you pause the game. All characters are unlocked from the beginning.

Below are timestamps for every character. I go through them in the same order as the in-game character select.

TIMELINE:

#1 – Rashid – 0:05
#2 – R. Mika – 0:19
#3 – Chun-Li – 0:34
#4 – Ryu – 0:47
#5 – Ken – 1:02
#6 – Cammy – 1:16
#7 – Vega – 1:28
#8 – Necalli – 1:42
#9 – Laura – 2:07
#10 – Zangief – 2:18
#11 – Karin – 2:32
#12 – Nash – 2:47
#13 – M. Bison – 3:00
#14 – Birdie – 3:16
#15 – Dhalsim – 3:26
#16 – F.A.N.G. – 3:43